Kalrez® FFKM Material Guide

Kalrez® FFKM Material Guide

Kalrez® perfluoroelastomers combine outstanding chemical resistance with the highest continuous temperature rating in the industry. This guide summarises the major grades, qualification requirements, and design tips for semiconductor, pharmaceutical, and refinery applications.

## Grade Comparison
| Grade | Temperature Range | Target Applications | Notes |
| — | — | — | — |
| 4079 | -20 °C to +316 °C | Semiconductor plasma etch, vacuum systems | Low compression set, good plasma resistance |
| Spectrum™ 6375 | -15 °C to +275 °C | Chemical process, amines, steam | Broad chemical compatibility, ideal for mixed streams |
| 7075 | 0 °C to +327 °C | High-temperature chemical loops | High modulus and low compression set for static seals |
| Spectrum™ 6380 | -20 °C to +260 °C | Sour gas, amines, steam | Enhanced amine resistance and mechanical strength |
| 9100 | -15 °C to +300 °C | Semiconductor CVD/etch with low metals | Low particle, ultra-clean formulation |

## Selection Checklist
1. **Process media** – identify acids, amines, solvents, steam, and cleaning agents.
2. **Temperature profile** – include upset conditions, thermal cycling rate, and maximum bake-out temperature.
3. **Seal type** – static vs. dynamic, hardware gap, pressure load, and potential outgassing requirements.
4. **Compliance** – SEMI F57, FDA, USP Class VI, ATEX, oxygen compatibility, or refinery specifications.
5. **Documentation** – confirm manufacturer certificate of analysis, batch traceability, and lot release data.

## Engineering Practices
– Maintain static compression between 15–25 %; consider anti-extrusion rings above 10 MPa differential pressure.
– For dynamic seals, specify 75–80 A hardness and polished hardware (Ra ≤ 0.2 µm).
– Avoid sharp corners in glands; design radii and lead-ins to prevent nicks during installation.
– Pre-bake seals (per manufacturer guidelines) before ultra-clean semiconductor service to reduce outgassing.
– Store sealed packaging below 30 °C and protect from UV; respect Kalrez shelf-life guidance.

## Testing Matrix
| Requirement | Recommended Test | Acceptance |
| — | — | — |
| Chemical compatibility | ASTM D471 immersion in process media | Volume change ≤10 % |
| High-temperature aging | ASTM D573 @ operating peak | Hardness increase ≤10 |
| Compression set | ASTM D395 Method B | ≤30 % at process temperature |
| Plasma resistance | Vendor plasma test (e.g., O₂/CF₄) | Minimal mass loss / cracking |
| Cleanliness | SEMI F57 / ICP-MS metal analysis | Meets tool manufacturer limits |

## Related Resources
– [FFKM Perfluoroelastomer Guide](/materials/ffkm/) – broad overview and alternatives.
– [Design Services](/services/design-services/) – FEA, groove optimisation, validation planning.
– [Custom Manufacturing](/services/custom-manufacturing/) – prototype-to-production with Kalrez supply chain integration.

## Partner With Our Engineering Team
Share your media matrix, thermal envelope, and target launch date through the [FFKM quote form](/quote/ffkm/). A senior applications engineer will respond within one business day with a shortlist of Kalrez® grades, validation plan recommendations, and a procurement roadmap aligned to your schedule.

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